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Recent progress in electric-field assisted combustion: a brief review

《能源前沿(英文)》 2022年 第16卷 第6期   页码 883-899 doi: 10.1007/s11708-021-0770-z

摘要: The control of combustion is a hot and classical topic. Among the combustion technologies, electric-field assisted combustion is an advanced techno-logy that enjoys major advantages such as fast response and low power consumption compared with thermal power. However, its fundamental principle and impacts on the flames are complicated due to the coupling between physics, chemistry, and electromagnetics. In the last two decades, tremendous efforts have been made to understand electric-field assisted combustion. New observations have been reported based on different combustion systems and improved diagnostics. The main impacts, including flame stabilization, emission reduction, and flame propagation, have been revealed by both simulative and experimental studies. These findings significantly facilitate the application of electric-field assisted combustion. This brief review is intended to provide a comprehensive overview of the recent progress of this combustion technology and further point out research opportunities worth investigation.

关键词: electric field     combustion     flame stabilization     emission reduction     flame propagation    

Transient process of methane-oxygen diffusion flame-street establishment in a microchannel

《能源前沿(英文)》 2022年 第16卷 第6期   页码 988-999 doi: 10.1007/s11708-021-0755-y

摘要: “Flame-street” is an interesting diffusion flame behavior in which a series of flame-segments is separately distributed along the mixing layer in a narrow channel. This experimental phenomenon was experimentally and numerically investigated with the focus on the steady-state, thermo-chemical flame structures in previous literature. In the present paper, the dynamic formation process of a methane-oxygen diffusion flame-street structure was simulated with a reacting flow solver developed based on the open-source framework OpenFOAM. By imposing a certain amount of ignition-energy near the channel outlet, a reaction-kernel was formed and bifurcated. Subsequently, three separate flames were consecutively generated from this kernel and propagated within the channel. The whole process was completed within 15 ms and all the discrete flames were eventually in a steady-state. Interestingly, different propagation features were observed for the three flame segments: The leading flame experienced a flame shape/type change from a tribrachial structure in its fast-propagating phase to a long, trailing diffusion tail after being anchored to the inlet. The successive flame had a much lower propagation speed, keeping its two wing-like (fuel-lean premixed and fuel-rich premixed) structure while moving toward its stabilization location, which was approximately in the middle of the channel. The last flame, after the ignition source was turned-off, was immediately convected a bit downstream, and eventually featured a similar two-branch-like structure as the second one. Moreover, chemical insights for the premixed and diffusion branches of the leading flame were also provided with the change of significance of some key elementary reactions focused on, in order to attain a detailed profiling of the flame-type transition. This paper is a first-ever one discussing the transient formation of flame-streets in literature and is believed to be useful for obtaining a comprehensive understanding of this unique flame characteristics from a dynamic point of view.

关键词: micro-combustion     flame-street     diffusion flame     mixing layer     flame propagation speed    

Cu/Cr co-stabilization mechanisms in a simulated AlO-FeO-CrO-CuO waste system

《环境科学与工程前沿(英文)》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1408-4

摘要:

• Cu and Cr can be mostly incorporated into CuFexAlyCr2xyO4 with a spinel structure.

关键词: Spinel structure     Copper     Chromium     Co-stabilization     Thermal treatment    

NC flame pipe cutting machine tool based on open architecture CNC system

Xiaogen NIE, Yanbing LIU

《机械工程前沿(英文)》 2009年 第4卷 第2期   页码 147-152 doi: 10.1007/s11465-009-0025-x

摘要: Based on the analysis of the principle and flame movement of a pipe cutting machine tool, a retrofit NC flame pipe cutting machine tool (NFPCM) that can meet the demands of cutting various pipes is proposed. The paper deals with the design and implementation of an open architecture CNC system for the NFPCM, many of whose aspects are similar to milling machines; however, different from their machining processes and control strategies. The paper emphasizes on the NC system structure and the method for directly creating the NC file according to the cutting type and parameters. Further, the paper develops the program and sets up the open and module NC system.

关键词: flame pipe cutting     flame incision tracks     CNC     open architecture CNC system    

Experimental study on the laminar flame speed of hydrogen/natural gas/air mixtures

Chen DONG, Qulan ZHOU, Xiaoguang ZHANG, Qinxin ZHAO, Tongmo XU, Shi’en HUI

《化学科学与工程前沿(英文)》 2010年 第4卷 第4期   页码 417-422 doi: 10.1007/s11705-010-0515-8

摘要: Laminar flame speeds of hydrogen/natural gas/air mixtures have been measured over a full range of fuel compositions (0–100% volumetric fraction of H ) and a wide range of equivalence ratio using Bunsen burner. High sensitivity scientific CCD camera is use to capture the image of laminar flame. The reaction zone area is employed to calculate the laminar flame speed. The initial temperature and pressure of fuel air mixtures are 293 K and 1 atm. The laminar flame speeds of hydrogen/air mixture and natural gas/air mixture reach their maximum values 2.933 and 0.374 m/s when equivalence ratios equal to 1.7 and 1.1, respectively. The laminar flame speeds of hydrogen/natural gas/air mixtures rise with the increase of volumetric fraction of hydrogen. Moreover, the increase in laminar flame speed as the volumetric fraction of hydrogen increases presents an exponential increasing trend versus volumetric fraction of hydrogen. Empirical formulas to calculate the laminar flame speeds of hydrogen, natural gas, and hydrogen/natural gas mixtures are also given. Using these formulas, the laminar flame speed at different hydrogen fractions and equivalence ratios can be calculated.

关键词: laminar flame speed     experimental study     Bunsen flame    

Microwave enhanced stabilization of copper in artificially contaminated soil

Hua ZHANG, Zhiliang ZHU, Noboru YOSHIKAWA

《环境科学与工程前沿(英文)》 2011年 第5卷 第2期   页码 205-211 doi: 10.1007/s11783-010-0290-2

摘要: Microwave processing was used to stabilize copper ions in soil samples. Its effects on the stabilization efficiency were studied as a function of additive, microwave power, process time, and reaction atmosphere. The stabilization efficiency of the microwave process was evaluated based on the results of the toxicity characteristic leaching procedure (TCLP) test. The results showed that the optimal experimental condition contained a 700 W microwave power, 20 min process time and 3 iron wires as the additive, and that the highest stabilization efficiency level was more than 70%. In addition, the different reaction atmospheres showed no apparent effect on the stabilization efficiency of copper in the artificially contaminated soil. According to the result of the Tessier sequential extraction, the partial species of copper in the contaminated soil was deduced to transform from unstable species to stable states after the microwave process.

关键词: microwave     copper     stabilization    

Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and

《能源前沿(英文)》 2022年 第16卷 第2期   页码 263-276 doi: 10.1007/s11708-021-0791-7

摘要: The laminar flame speeds of ammonia mixed with syngas at a high pressure, temperature, and different syngas ratios were measured. The data obtained were fitted at different pressures, temperatures, syngas ratios, and equivalence ratios. Four kinetic models (the Glarborg model, Shrestha model, Mei model, and Han model) were compared and validated with experimental data. Pathway, sensitivity and radical pool analysis are conducted to find out the deep kinetic insight on ammonia oxidation and NO formation. The pathway analysis shows that H abstraction reactions and NHi combination reactions play important roles in ammonia oxidation. NO formation is closely related to H, OH, the O radical produced, and formation reactions. NO is mainly formed from reaction, HNO+ H= NO+ H2. Furthermore, both ammonia oxidation and NO formation are sensitive to small radical reactions and ammonia related reactions.

关键词: ammonia mixed with syngas     laminar flame speed     kinetic model     sensitivity analysis     pathway analysis    

Molybdenum disulfide@nickel phyllosilicate hybrid for improving the flame retardancy and wear resistance

《化学科学与工程前沿(英文)》 2023年 第17卷 第12期   页码 2114-2126 doi: 10.1007/s11705-023-2357-1

摘要: In this study, nickel phyllosilicate was synthesized based on molybdenum disulfide (MoS2@NiPS) by the sol-gel method, and then MoS2@NiPS was used to prepare epoxy composites. The thermal stability, flame retardancy, and frictional performances of epoxy composites were studied. With the addition of 3 wt% MoS2@NiPS, the epoxy composite increased the limiting oxygen index from 23.8% to 26.1% and reduced the vertical burning time from 166 s for epoxy resin to 35 s. The residual char of the epoxy composite increased from 11.8 to 20.2 wt%. MoS2@NiPS promoted the graphitization of the residual char, and facilitated the formation of a dense and continuous char layer, thereby improving the fire safety of epoxy resin. The epoxy composite with 3 wt% MoS2@NiPS had excellent wear resistance property with a wear rate of 2.19 × 10−5 mm3·N–1·m–1, which was 68.8% lower than that of epoxy resin. This study presented a practical approach to improve the frictional and fire resistance of epoxy composites.

关键词: molybdenum disulfide     nickel phyllosilicate     epoxy resin     flame retardancy    

A low-density polyethylene composite with phosphorus-nitrogen based flame retardant and multi-walledcarbon nanotubes for enhanced electrical conductivity and acceptable flame retardancy

Yong Luo, Yuhui Xie, Renjie Chen, Ruizhi Zheng, Hua Wu, Xinxin Sheng, Delong Xie, Yi Mei

《化学科学与工程前沿(英文)》 2021年 第15卷 第5期   页码 1332-1345 doi: 10.1007/s11705-021-2035-0

摘要: Design and exploitation of flame retardant polymers with high electrical conductivity are desired for polymer applications in electronics. Herein, a novel phosphorus-nitrogen intumescent flame retardant was synthesized from pentaerythritol octahydrogen tetraphosphate, phenylphosphonyl dichloride, and aniline. Low-density polyethylene was combined with the flame retardant and multi-walled carbon nanotubes to form a nanocomposite material via a ball-milling and hot-pressing method. The electrical conductivity, mechanical properties, thermal performance, and flame retardancy of the composites were investigated using a four-point probe instrument, universal tensile machine, thermogravimetric analysis, and cone calorimeter tests, respectively. It was found that the addition of multi-walled carbon nanotubes can significantly improve the electrical conductivity and mechanical properties of the low-density polyethylene composites. Furthermore, the combination of multi-walled carbon nanotubes and phosphorus–nitrogen flame retardant remarkably enhances the flame retardancy of matrixes with an observed decrease of the peak heat release rate and total heat release of 49.8% and 51.9%, respectively. This study provides a new and effective methodology to substantially enhance the electrical conductivity and flame retardancy of polymers with an attractive prospect for polymer applications in electrical equipment.

关键词: MWCNTs     PEPA     electrical conductivity     flame retardant     low density polyethylene    

Cement-based solidification/stabilization of contaminated soils by nitrobenzene

Jianguo LIU, Xiaoqin NIE, Xianwei ZENG, Zhaoji SU

《环境科学与工程前沿(英文)》 2012年 第6卷 第3期   页码 437-443 doi: 10.1007/s11783-012-0406-y

摘要: The cement-based solidification/stabilization (S/S) of nitrobenzene (NB) contaminated soils, with cement and lime as binders, sodium silicate solution and powder activated carbon (PAC) as additives, was optimized through an orthogonal experiment, and S/S efficiency was estimated by both leaching test and volatilization measurement. The leaching test results showed that the factors affecting S/S efficiency were NB concentration, cement-to-lime ratio and binder-to-soils ratio, in sequence. With increasing curing time, the leaching concentration of NB between different levels of the same factor in the orthogonal experiment decreased, and less than 9% NB leached out from the 28 d cured samples. The volatilization measurement results indicated that 0.5‰ of NB was volatilized during the mixing and curing processes for the samples without PAC in the 28 d cycle, whereas adding 2 wt% and 5 wt% PAC, with respect to the weight of contaminated soils, could reduce NB volatilization to half of its original values either during the mixing or curing process. The optimizing formula, that is, contaminated soils (dry weight):cement:lime= 100:25:25, with 5 wt% additional sodium silicate and 2 wt% additional PAC, was applied to the engineering application of NB contaminated soils. Both the leaching test results of the product and the ambient air quality monitoring results met related regulations during the treating process.

关键词: solidification/stabilization     nitrobenzene     contaminated soils     powder activated carbon    

A method of determining flame radiation fraction induced by interaction burning of tri-symmetric propane

Jie JI, Junrui DUAN, Huaxian WAN

《能源前沿(英文)》 2022年 第16卷 第6期   页码 1017-1026 doi: 10.1007/s11708-020-0716-x

摘要: The interaction of multiple fires may lead to a higher flame height and more intense radiation flux than a single fire, which increases the possibility of flame spread and risks to the surroundings. Experiments were conducted using three burners with identical heat release rates (HRRs) and propane as the fuel at various spacings. The results show that flames change from non-merging to merging as the spacing decreases, which result in a complex evolution of flame height and merging point height. To facilitate the analysis, a novel merging criterion based on the dimensionless spacing / was proposed. For non-merging flames ( / >0.368), the flame height is almost identical to a single fire; for merging flames ( / ≤0.368), based on the relationship between thermal buoyancy and thrust (the pressure difference between the inside and outside of the flame), a quantitative analysis of the flame height, merging point height, and air entrainment was formed, and the calculated merging flame heights show a good agreement with the measured experimental values. Moreover, the multi-point source model was further improved, and radiation fraction of propane was calculated. The data obtained in this study would play an important role in calculating the external radiation of propane fire.

关键词: flame interaction     air entrainment     flame height     multi-point source model     thermal radiation    

Flame-retardant properties of

Kumar Sai SMARAN, Rajashekar BADAM, Raman VEDARAJAN, Noriyoshi MATSUMI

《能源前沿(英文)》 2019年 第13卷 第1期   页码 163-171 doi: 10.1007/s11708-018-0554-2

摘要: This paper focuses on the superiority of organic-inorganic hybrid ion-gel electrolytes for lithium-ion batteries (LiBs) over commercial electrolytes, such as 1 M LiPF in 1:1 ethylene carbonate (EC): dimethyl carbonate (DMC) {1 M LiPF -EC: DMC}, in terms of their flame susceptibility. These ion-gel electrolytes possess ionic liquid monomers, which are confined within the borosilicate or silicate matrices that are ideal for non-flammability. Naked flame tests confirm that the organic-inorganic hybrid electrolytes are less susceptible to flames, and these electrolytes do not suffer from a major loss in terms of weight. In addition, the hybrids are self-extinguishable. Therefore, these hybrids are only oxidized when subjected to a flame unlike other commercial electrolytes used in lithium-ion batteries. Supplementary analyses using differential scanning calorimetric studies reveal that the hybrids are glassy until the temperature reaches more than 100°C. The current results are consistent with previously published data on the organic-inorganic hybrids.

关键词: inorganic polymeric borosilicate network     organic-inorganic hybrids     self-extinguishability     nonflammability     lithium batteries     flame-retardants    

Analysis and stabilization control of a voltage source controlled wind farm under weak grid conditions

《能源前沿(英文)》 2022年 第16卷 第6期   页码 943-955 doi: 10.1007/s11708-021-0793-5

摘要: This paper investigates and discusses the interaction stability issues of a wind farm with weak grid connections, where the wind turbines (WTs) are controlled by a new type of converter control strategy referred to as the voltage source (VS) control. The primary intention of the VS control method is to achieve the high-quality inertial response capability of a single WT. However, when it is applied to multiple WTs within a wind farm, its weak-grid performance regarding the stability remains concealed and needs to be clarified. To this end, a frequency domain model of the wind farm under the VS control is first developed. Based on this model and the application of a stability margin quantification index, not only the interactions between the wind farm and the weak grid but also those among WTs will be systematically assessed in this paper. A crucial finding is that the inertial response of VS control has negative impacts on the stability margin of the system, and the dominant instability mode is more related to the interactions among the WTs rather than the typical grid-wind farm interaction. Based on this knowledge, a stabilization control strategy is then proposed, aiming for stability improvements of VS control while fulfilling the demand of inertial responses. Finally, all the results are verified by time-domain simulations in power systems computer aided design/electromagnetic transients including DC(PSCAD/EMTDC).

关键词: weak grids     voltage source (VS) control     wind turbine (WT)     stabilization control     wind farm     inertial response    

The use of fine portions from construction and demolition waste for expansive soil stabilization: A review

Mgboawaji Claude UJILE; Samuel Jonah ABBEY

《结构与土木工程前沿(英文)》 2022年 第16卷 第7期   页码 803-816 doi: 10.1007/s11709-022-0835-z

摘要: Construction and demolition waste (CDW) are the largest waste products in the world today and competes as a viable recycled additive material in place of natural aggregates. Due to the increase in compressive strength of different mix proportions of CDW, it is also considered for reuse in concrete and subbase construction. This study shows the effect of CDW in expansive soil stabilization. The chemical and mechanical properties of these materials have shown that they are capable of developing compressive strength properties for replacement of cement with significant reduction in carbon emission. The inherent compositional properties of recycled CDW compared in this review suggests that CDW have good filler properties in highly expansive soils. Mixtures of crushed brick and recycled aggregates characterised based on chemical properties of different replacement ratios suggests that CDW of good-quality aggregates reduces swell potential of expansive soils and increased mechanical strength in pavement construction.

关键词: mixed fine portions     construction and demolition waste     expansive soil     soil stabilization    

Phosphate-induced differences in stabilization efficiency for soils contaminated with lead, zinc, and

Jie Ren, Zhuo Zhang, Mei Wang, Guanlin Guo, Ping Du, Fasheng Li

《环境科学与工程前沿(英文)》 2018年 第12卷 第2期 doi: 10.1007/s11783-018-1006-2

摘要: Phosphates can cost-effectively decrease the mobility of Pb in contaminated soils. However, Pb always coexists with other metals in soil, their competitive reactions with phosphates have not been tested. In this study, the abilities of KH PO , K HPO , and K PO to stabilize Pb, Zn, and Cd in soils contaminated with a single metal or a ternary metal for different phosphorus/metal molar ratios were investigated. Results indicated that the stabilization efficiency of KH PO , K HPO , and K PO for Pb, Zn, and Cd in single metal contaminated soil (P/M ratio 0.6) was 96.00%–98.74%, 33.76%–47.81%, and 9.50%–55.79%, respectively. Competitive stabilization occurred in the ternary system, Pb exhibited a strong competition, the stabilization efficiency of Zn and Cd reduced by 23.50%–31.64%, and 7.10%–39.26%, respectively. Pyromorphite and amorphous lead phosphate formed with excess KH PO or K HPO addition, while K PO resulted in the formation of a hydroxypyromorphite precipitate. Amorphous Zn and Cd phosphates and hydroxides were the primary products. The immobilization rate of Zn and Cd depends on pH, and increased significantly in response to the excess phosphate application. This approach provides insight into phosphate-induced differences in stabilization efficiency in soils contaminated with multiple metals, which is of theoretical and engineering significance.

关键词: Heavy metals     Metal-contaminated soil     Phosphate     Competitive stabilization    

标题 作者 时间 类型 操作

Recent progress in electric-field assisted combustion: a brief review

期刊论文

Transient process of methane-oxygen diffusion flame-street establishment in a microchannel

期刊论文

Cu/Cr co-stabilization mechanisms in a simulated AlO-FeO-CrO-CuO waste system

期刊论文

NC flame pipe cutting machine tool based on open architecture CNC system

Xiaogen NIE, Yanbing LIU

期刊论文

Experimental study on the laminar flame speed of hydrogen/natural gas/air mixtures

Chen DONG, Qulan ZHOU, Xiaoguang ZHANG, Qinxin ZHAO, Tongmo XU, Shi’en HUI

期刊论文

Microwave enhanced stabilization of copper in artificially contaminated soil

Hua ZHANG, Zhiliang ZHU, Noboru YOSHIKAWA

期刊论文

Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and

期刊论文

Molybdenum disulfide@nickel phyllosilicate hybrid for improving the flame retardancy and wear resistance

期刊论文

A low-density polyethylene composite with phosphorus-nitrogen based flame retardant and multi-walledcarbon nanotubes for enhanced electrical conductivity and acceptable flame retardancy

Yong Luo, Yuhui Xie, Renjie Chen, Ruizhi Zheng, Hua Wu, Xinxin Sheng, Delong Xie, Yi Mei

期刊论文

Cement-based solidification/stabilization of contaminated soils by nitrobenzene

Jianguo LIU, Xiaoqin NIE, Xianwei ZENG, Zhaoji SU

期刊论文

A method of determining flame radiation fraction induced by interaction burning of tri-symmetric propane

Jie JI, Junrui DUAN, Huaxian WAN

期刊论文

Flame-retardant properties of

Kumar Sai SMARAN, Rajashekar BADAM, Raman VEDARAJAN, Noriyoshi MATSUMI

期刊论文

Analysis and stabilization control of a voltage source controlled wind farm under weak grid conditions

期刊论文

The use of fine portions from construction and demolition waste for expansive soil stabilization: A review

Mgboawaji Claude UJILE; Samuel Jonah ABBEY

期刊论文

Phosphate-induced differences in stabilization efficiency for soils contaminated with lead, zinc, and

Jie Ren, Zhuo Zhang, Mei Wang, Guanlin Guo, Ping Du, Fasheng Li

期刊论文